Studies on Zn(II) monohydroxyphenyl mesoporphyrinic complexes: Synthesis and characterization

Studies on Zn(II) monohydroxyphenyl mesoporphyrinic complexes: Synthesis and characterization

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A series of four Zn(II) complexes with asymmetrical porphyrinic ligands were synthesized: [5-(4-hydroxyphenyl)-10,15,20-triphenyl-21H,23H-porphinato]Zn(II) (Zn(II)TPPOHP), [5-(3-hydroxyphenyl)-10,15,20-triphenyl-21H,23H- -porphinato]Zn(II) (Zn(II)TPPOHM), [5-(2-hydroxyphenyl)-10,15,20-triphenyl- -21H,23H-Zn(II)-porphinato]Zn(II) (Zn(II)TPPOHO) and the well-known (5,10,15,20- -tetraphenyl-21H,23H-porphinato]Zn(II) (Zn(II)TPP) as reference, in a 1:1 mole ratio.In all cases, the free-base porphyrin served as a tetradentate ligand through the four pyrrole nitrogen atoms.The complexes were characterized by elemental analysis, click here FTIR and UV-Vis spectroscopy, which fully read more confirmed the structure of the complexes.UV-Vis showed that the spectral absorption of the four complexes was blue-shifted by at least 50 nm compared to that of the free ligands.Also important structural data were obtained from several different NMR experiments (including 1H-NMR, 13C-NMR, DEPT, COSY, HMBC and HMQC).

Influences of external substituents on the porphyrin ring were observed.